benzyl-methyl-selenonium-methylide-tribromo-indate(III) | 849706-58-7

• 英文名称: benzyl-methyl-selenonium-methylide-tribromo-indate(III)
• CAS: 849706-58-7
• 化学式: C₉H₁₂Br₃InSe
• 分子量: 553.686
• InChiKey: HCXDIIJDZPVHDM-USOZLSCGSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4-二氧六环 、 indium(I) bromide 、 benzyl methyl selenide 、 二溴甲烷 以 1,4-二氧六环 为溶剂， 以40%的产率得到benzyl-methyl-selenonium-methylide-tribromo-indate(III)
  参考文献：
  名称：

  Synthesis and molecular structures of dialkylselenonium methylide complexes of indium tribromide

  摘要：

  The reaction of bromomethyl-dibromo-indium(III), Br2InCH2Br with dialkylselenides, (RSeR2)-Se-1 (R-1 = CH3, R-2 = CH2C6H5; R-1 = C2H5, R-2 = CH2C6H5; R-1 = R-2 = CH2C6H5) afforded the corresponding dialkylselenonium methylide complexes of indium tribromide, (Br3InCH2SeRR2)-R-1, which were fully characterized by NMR spectroscopy and single crystal X-ray diffraction studies. (c) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.11.050