Na{((η5-C5H5)(CO)2Mn)2(μ-H)} | 119366-71-1

• 英文名称: Na{((η5-C5H5)(CO)2Mn)2(μ-H)}
• CAS: 119366-71-1
• 化学式: C₁₄H₁₁Mn₂O₄*Na
• 分子量: 376.105
• InChiKey: KNBSCHZZAGJUTJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Na{((η5-C5H5)(CO)2Mn)2(μ-H)} 、 tin(II) bromide 、 4,7,13,16,21,24-六氧-1,10-二氮双环[8.8.8]二十六烷 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Trigonal-planar koordiniertes Sn0 in [{Cp′(CO)2Mn} 2SnHal]−:Zinnverbindungen vom “Iniden”-Typ

  摘要：

  The hydride complexes Na.([{L(CO)2Mn}2H]) (Na.1) (L = Cp, Cp', Cp star), react with tin halides Sn(Hal)2 to give dimanganastannacumulene compounds [L(CO)2Mn = Sn = Mn(CO)2L] (2). For L = Cp star the compound [Cp star(CO)2Mn = Sn = Mn(CO)2Cp star] (2a), which is already known, can be isolated. For L = Cp, Cp', 2 is only available in solution. In the presence of 2,2,2-Crypt, the cumulene intermediates 2 add the halide present in the solution forming the anionic ''inidene'' compounds [L(CO)2Mn Sn(Hal) Mn(CO)2L]- (4). For L = Cp' the compounds 4 (Hal = Cl (4a); Hal = Br (4b); Hal = I (4c)) are characterized by X-ray analyses. The compounds 4 show trigonal planar coordination around the bridging tin(0). Their geometry thus corresponds to the one observed at their isoelectronic neutral analogues with group 15 bridging elements [L(CO)2Mn...XR...Mn(CO)2L] (X = P, As, Sb, Bi). Synthesis and properties of the tin(0) complexes 4, as well as of tin(II) derivatives of type [{L(CO)2Mn}Sn(SR)3]- (3) are presented and discussed with regard to spectroscopic and structural data.

  DOI：

  10.1016/0022-328x(91)83243-w