6-ferrocenyl-2-thiocarbonyluracil | 271246-15-2

• 英文名称: 6-ferrocenyl-2-thiocarbonyluracil
• CAS: 271246-15-2
• 化学式: C₁₄H₁₂FeN₂OS
• 分子量: 312.175
• InChiKey: PDTLYUMQOJLKFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  6-ferrocenyl-2-thiocarbonyluracil 在 盐酸 、 氯乙酸 作用下， 以 水 为溶剂， 以98%的产率得到6-ferrocenyluracil
  参考文献：
  名称：

  Recognition and Encapsulation of an Electroactive Guest within a Dynamically Folded Polymer

  摘要：

  Diaminotriazine-functionalized polymer 1 folds in nonpolar media into unimolecular "micelles", in which the diaminotriazine units are inwardly directed to form a polar pocket analogous to the active sites found in proteins. To explore the possibility of site isolation within this pocket we synthesized the redox active guest 6-ferrocenyluracil 2. Encapsulation of guest 2 by polymer 1 was established by NMR studies; functional site isolation was demonstrated through cyclic voltammetry studies.

  DOI：

  10.1021/ja993735g
• 作为产物：
  描述：

  3-ferrocenyl-3-ketoethyl propanoate 在 乙醇 、 sodium 作用下， 以 乙醇 为溶剂， 以89%的产率得到6-ferrocenyl-2-thiocarbonyluracil
  参考文献：
  名称：

  Recognition and Encapsulation of an Electroactive Guest within a Dynamically Folded Polymer

  摘要：

  Diaminotriazine-functionalized polymer 1 folds in nonpolar media into unimolecular "micelles", in which the diaminotriazine units are inwardly directed to form a polar pocket analogous to the active sites found in proteins. To explore the possibility of site isolation within this pocket we synthesized the redox active guest 6-ferrocenyluracil 2. Encapsulation of guest 2 by polymer 1 was established by NMR studies; functional site isolation was demonstrated through cyclic voltammetry studies.

  DOI：

  10.1021/ja993735g