dichloro[2,9-diformyl-1,10-phenanthrolinebis(2,6-diisopropylanil)]cobalt(II) | 478813-13-7

• 英文名称: dichloro[2,9-diformyl-1,10-phenanthrolinebis(2,6-diisopropylanil)]cobalt(II)
• CAS: 478813-13-7
• 化学式: C₃₈H₄₂Cl₂CoN₄
• 分子量: 684.677
• InChiKey: QIFMBEBDQAAYEX-HUECXYFMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride 、 2,9-diformyl-1,10-phenanthrolinebis(2,6-diisopropylanil) 以 乙醇 为溶剂， 以60%的产率得到dichloro[2,9-diformyl-1,10-phenanthrolinebis(2,6-diisopropylanil)]cobalt(II)
  参考文献：
  名称：

  Late transition metal complexes bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands: synthesis, characterization and their ethylene activity

  摘要：

  A series of iron, cobalt and nickel halide complexes, LMX2 (M = Fe, X = Cl; M = Co, X = Cl, M = N-1, X = Br) bearing 2,9-bis(imino)-1,10-phenanthrolinyl ligands [L = 2,9-(ArNCH)(2)C12H6N2] were synthesized. The solid-state structures of 4 and 7 have been determined by single-crystal X-ray diffraction study. Treatment of the complexes LMX2 with methylaluminoxane (MAO) leaded to activate ethylene as oligomerization catalysts. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01623-6