bis(2,2'-bipyridine)(N,N'-diethyldithiocarbamate)ruthenium(II) hexafluorophosphate | 97279-20-4

• 英文名称: bis(2,2'-bipyridine)(N,N'-diethyldithiocarbamate)ruthenium(II) hexafluorophosphate
• 英文别名: [Ru(bipy)2Ru(S2CN(C2H5)2)]
• CAS: 97279-20-4
• 化学式: C₂₅H₂₆N₅RuS₂*F₆P
• 分子量: 706.681
• InChiKey: ZWCICFCIZAQZFP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 sodium diethyldithiocarbamate trihydrate 以 乙醇 、 水 为溶剂， 以92%的产率得到bis(2,2'-bipyridine)(N,N'-diethyldithiocarbamate)ruthenium(II) hexafluorophosphate
  参考文献：
  名称：

  Amide functionalised dithiocarbamate ruthenium(II) bis-bipyridyl receptors: A new class of redox-responsive anion sensor

  摘要：

  The synthesis of new amide functionalised ruthenium(II) bis- bipyridyl dithiocarbamate receptor molecules is described. These hosts have been shown to sense the binding of anions electrochemically. Proton NMR titration studies in dmso-d(6):MeCN-d(3) (1:1) solvent mixtures indicate that the receptors selectively bind dihydrogen phosphate. A single crystal X-ray structure of one receptor reveals the crucial role of amide - anion hydrogen bonding interactions in the binding of sulphate. Cyclic and square wave voltammetric investigations demonstrate that the receptors can sense the binding of anions electrochemically. The addition of dihydrogen phosphate induced the largest cathodic perturbation of the metal centred Ru(II)/(III) dithiocarbamate redox couple (Delta E = 180 mV). (C) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.02.030