| 468082-89-5

• CAS: 468082-89-5
• 化学式: C₄₇H₆₉OP₃Ru
• 分子量: 844.056
• InChiKey: ZXJSGONZQSBTLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 氢气 在 NaBPh₄ 、 K₂CO₃ 作用下， 以 甲醇 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Reactions of hydrogen with ruthenium and osmium complexes containing tridentate ligands Cy2PCH2CH(CH2)2PCy2 and 2,6-(Ph2PCH2)2C6H3

  摘要：

  Reaction of cis-1,4-dichlorobut-2-ene with dicyclohexylphosphine in the presence of KI in acetone produces [cis-Cy2PHCH2CH = CHCH2PHCy2]I-2 which is converted to cis-Cy2PCH2CH = CHCH2PCy2 on treatment with NaOH. Reactions of cis-Cy2PCH2CH = CHCH2PCy2 With MHCl(CO)(PPh3)(3) (M = Ru, Os) yield MHCl(CO)(PPh3)(Cy2PCH2CH = CHCH2PCy2). The ruthenium complex RuCl(CO)(PPh3)(Cy2PCH2CH(CH2)(2)PCy2) is obtained by refluxing RuHCl(CO)(PPh3)(Cy2PCH2CH = CHCH2PCy2) in methanol-CH2Cl2. Reaction of RuCl(CO)(PPh3)(Cy2PCH2CH(CH2)(2)PCy2) with H-2 in the presence of NaBPh4 produces RuHCl(CO)(PPh3)(Cy-P(CH2)(4)PCy2). Reaction of OsCl(PPh3)(2,6-(Ph2PCH2)(2)C6H3) with H-3 produces OsCl(H...H)(PPh3)(2,6-(Ph2PCH2)(2)C6H3) which contains an elongated dihydrogen ligand. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00750-8