(hexakis(2-pyridyloxy)cyclotriphosphazene)copper(I) hexafluorophosphate | 868830-98-2

• 英文名称: (hexakis(2-pyridyloxy)cyclotriphosphazene)copper(I) hexafluorophosphate
• CAS: 868830-98-2
• 化学式: C₃₀H₂₄N₉O₆P₃*Cu*F₆P
• 分子量: 908.009
• InChiKey: AJQVSIKLPBDCCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetrakis(actonitrile)copper(I) hexafluorophosphate 、 hexakis(2-pyridyloxy)cyclotriphosphazene 以 not given 为溶剂， 生成 (hexakis(2-pyridyloxy)cyclotriphosphazene)copper(I) hexafluorophosphate
  参考文献：
  名称：

  Polymer Building Blocks:  Self-Assembly of Silver(I) Cyclotriphosphazene Cationic Columns

  摘要：

  The multimodal ligand hexakis(2-pyridyloxy)cyclotriphosphazene (L) and its 4-methyl-2-pyridyloxy analogue (MeL) react with Ag(I) to afford {[AgL](+)}(infinity) supramolecular cationic columns via self-assembly, with the anions occupying the intercolumnar channels. In contrast, the reaction of MeL with Cu(I) yields a dimetallic Cu(II) complex containing mu-OH and mu-4-methyl-2-pyridyloxylato bridges.

  DOI：

  10.1021/ic051334y