| 208708-96-7

• CAS: 208708-96-7
• 化学式: C₁₈H₄₀B₁₅NOP₂PtS₂
• 分子量: 769.846
• InChiKey: APICIHPGCVYKCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis-[Me2Pt(PMe2Ph)2] 、 nido-9'-thiadecaborano-{6',7':5,6}-nido-9-thiadecaborane 以 二氯甲烷 为溶剂， 以4%的产率得到
  参考文献：
  名称：

  Macropolyhedral boron-containing cluster chemistry. [PtMe2(PMe2Ph)2] as a cluster metallating agent. Isolation and characterisation of nineteen-vertex [(PMe2Ph)HPt-η4-syn-B18H19(PMe2Ph)] and eighteen-vertex [(PMe2Ph)2PtS2B15H14(NHCOMe]

  摘要：

  [PtMe2(PMe2Ph)(2)] reacts quantitatively with [nido-B10H14], [arachno-4-SB8H12] and [nido-7-SB10H12] to give [(PMe2Ph)(2)PtB10H12], [(PMe2Ph)(2)PtSB8H10] and [(PMe2Ph)(2)PtSB10H10]. With [syn-B18H22] it gives nineteen-vertex [(PMe2Ph)HPtn(4)-syn-B18H19(PMe2Ph)](1) and only smaller amounts of [(PMe2Ph)(2)Pt-n(4)-syn-B18H20], whereas with [(anti)-9,9'-S2B16H16] a complex product mixture is generated from which eighteen-vertex [(PMe2Ph)(2)Pts(2)B(15)H(14)(NHCOMe)](1) is isolatable after treatment with MeCN in air. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00666-9