CpMo(CO)3(SCOCH2Cl) | 919351-38-5

• 英文名称: CpMo(CO)3(SCOCH2Cl)
• CAS: 919351-38-5
• 化学式: C₁₀H₇ClMoO₄S
• 分子量: 354.622
• InChiKey: PBAMWELEFCJXLX-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  tricarbonyl(η5-cyclopentadienyl)(hydrogensulfido)molybdenum 、 氯乙酰氯 以 乙醚 为溶剂， 以75%的产率得到CpMo(CO)3(SCOCH2Cl)
  参考文献：
  名称：

  Molybdenum S-bonded mono-thiocarboxylate complexes CpMo(CO)3SCOR: Structure of CpMo(CO)3SCOPh

  摘要：

  Monothiocarboxylate complexes of molybdenum of the type CPMO(CO)(3)SCOR [R = Me (1), CH2Cl (2), Ph (3), 4-C6H4NO, (4), 3,5-C6H3(NO2)(2)(5)] have been obtained by the reaction of the hydrosulfido complex, CPMO(CO)(3)SH, with acid chlorides. Complexes 1-5 have been characterized by IR and H-1-NMR spectroscopy, elemental analyses and by the single crystal X-ray diffraction of 3. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.06.021