Rational synthesis of trinuclear (WIr2) cluster from the 16-electron half-sandwich complex Cp*Ir[Se2C2(B10H10)]
摘要:
A trinuclear cluster {Cp*Ir[Se(2)C(2)(B(10)H(10))]}(2)W(CO)(2) (3) containing Ir-W bonding was obtained from the reaction of 16-electron complex Cp*Ir[Se(2)C(2)(B(10)H(10))] with [W(CO)(3)(py)(3)] in the presence of BF(3) (.) OEt(2), and its structure has been determined by X-ray crystallography. (C) 2004 Elsevier B.V. All rights reserved.