[tris(trimethylsilylmethyl)[60]fullerenyl](1,5-cyclooctadiene)rhodium(I) | 562107-43-1

• 英文名称: [tris(trimethylsilylmethyl)[60]fullerenyl](1,5-cyclooctadiene)rhodium(I)
• 英文别名: Rh[η5-C60(CH2SiMe3)3](1,5-cyclooctadiene)
• CAS: 562107-43-1
• 化学式: C₈₀H₄₅RhSi₃
• 分子量: 1193.4
• InChiKey: MPFRPXPCUZBPEP-NWXVKXGGSA-N

反应信息

• 作为产物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 以 四氢呋喃 为溶剂， 以91%的产率得到[tris(trimethylsilylmethyl)[60]fullerenyl](1,5-cyclooctadiene)rhodium(I)
  参考文献：
  名称：

  Synthesis of trialkyl[60]fullerene C60(CH2SiMe3)3H and its potassium and rhodium(I) complexes

  摘要：

  The reaction of [60]fullerene with Me3SiCH2MgCl in 1,2-Cl1C6H4/THF (1/1) under dry air afforded a bis-alkyl adduct, C-60(CH2SiMe3)(2) (1), in 54% yield. Treatment of I with Me3SiCH2MgCl in THF under argon then afforded a trialkyl[60]fullerene, C-60(CH2SiMe3)(3)H (2), in 37% yield. Further treatment of 2 with KO'Bu gave a potassium salt, [K(thf)(n)][C-60(CH2SiMe3)(3)] (3), which was then converted to a C-s-symmetric Rh(l) complex, Rh[eta(5)-C-60(CH2SiMe3)(3)](1,5-cyclooctadiene) (4), in 91% yield. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.07.021