(1,2-dicarba-closo-dodecaborane-1,2-diselenolato)(pentamethylcyclopentadienyl)Ir(CO) | 847445-74-3

• 英文名称: (1,2-dicarba-closo-dodecaborane-1,2-diselenolato)(pentamethylcyclopentadienyl)Ir(CO)
• 英文别名: [η5-pentamethylcyclopentadienyl-[1,2-dicarba-closo-dodecaborane(12)-diselenolato]iridium(CO)]；η5-pentamethylcyclopentadienyliridium(CO)[1,2-dicarba-closo-dodecaborane(12)-diselenolato)]；η5-C5Me5Ir(CO)[Se2C2(B10H10)]
• CAS: 847445-74-3
• 化学式: C₁₃H₂₅B₁₀IrOSe₂
• 分子量: 655.591
• InChiKey: UPUPCHSTSYHJKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  η5-pentamethylcyclopentadienyl-[1,2-dicarba-closo-dodecaborane(12)-diselenolato]iridium 、 一氧化碳 以 二氯甲烷 为溶剂， 生成 (1,2-dicarba-closo-dodecaborane-1,2-diselenolato)(pentamethylcyclopentadienyl)Ir(CO)
  参考文献：
  名称：

  Rational synthesis of trinuclear (WIr2) cluster from the 16-electron half-sandwich complex Cp*Ir[Se2C2(B10H10)]

  摘要：

  A trinuclear cluster {Cp*Ir[Se(2)C(2)(B(10)H(10))]}(2)W(CO)(2) (3) containing Ir-W bonding was obtained from the reaction of 16-electron complex Cp*Ir[Se(2)C(2)(B(10)H(10))] with [W(CO)(3)(py)(3)] in the presence of BF(3) (.) OEt(2), and its structure has been determined by X-ray crystallography. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.076

文献信息

• Synthesis and Structure of Heterometallic Clusters (IrCo₂, IrFe) Containing Bridging 1,2-Dicarba-<i>c</i><i>loso</i>-dodecaborane-1,2-dichalocogenolato Ligands
  作者：Jian-Qiang Wang、Xiufeng Hou、Linhong Weng、Guo-Xin Jin

  DOI：10.1021/om049185z

  日期：2005.2.1

  The 16-electron half-sandwich iridium complexes [Cp*IrE2C2(B10H10)}] [E = S (1a), Se (1b)] (Cp* = eta(5)-C5Me5) [Cp*Ir[E2C2(B10H10)] = eta(5)-pentamethylcyclopentadienyl-[1,2-dicarbacloso-dodecaborane(12)-dichalcogenolato]iridium] reacted with Co-2(CO)(8) in toluene solution to afford the trinuclear clusters [Cp*IrE2C2(B10H10)}]Co-2(CO)(5)} [E = S (2a), Se (2b)] and mononuclear complexes [Cp*Ir(CO)E2C2(B10H10)}] [E = S (3a), Se (3b)] as byproducts. Compounds 2a and 2b contain closed IrCo2 triangle geometry with one Co-Co and two Ir-Co bonds. The dinuclear IrFe complexes [Cp*IrE2C2(B10H10)}]Fe(CO)(3)} [E = S (4a), Se (4b)] were obtained from the reactions of 1a and 1b with Fe(CO)5 in the presence of Me3NO. The molecular structures of 2a, 2b, and 4b have been determined by X-ray crystallography.