| 107945-08-4

• CAS: 107945-08-4
• 化学式: C₃₀H₂₃IMnN₂O₅P
• 分子量: 704.339
• InChiKey: MWSOYTGGKPIJRK-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 AgCN 作用下， 以 二氯甲烷 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Synthesis of mono and binuclear carbonyl complexes of manganese with cyanide or thiocyanate ligands. X-ray crystal structure of [{fac-Mn(CO)3(phen)}2(μ-CN)]PF6

  摘要：

  DOI：

  10.1016/s0020-1693(00)84519-3
• 作为产物：
  描述：

  在 KI 作用下， 以 丙酮 为溶剂， 以84%的产率得到
  参考文献：
  名称：

  Synthesis of mono and binuclear carbonyl complexes of manganese with cyanide or thiocyanate ligands. X-ray crystal structure of [{fac-Mn(CO)3(phen)}2(μ-CN)]PF6

  摘要：

  DOI：

  10.1016/s0020-1693(00)84519-3

文献信息

• cis-trans-[{N3P3Cl4(C6H5)(PPh2)}Mn(CO)2(bipy){P(OPh)3}]PF6. A Cationic Manganese–Carbonyl Complex with a Phosphazenylphosphine Ligand
  作者：G. A. Carriedo、L. Fernández、P. Gómez、S. García-Granda、A. M. Velázquez

  DOI：10.1107/s0108270194006943

  日期：1995.1.15

  The structure of cis-trans-(bipyridine-N,N')dicarbonyl-[diphenyl(2-phenyl-4,4,6,6-tetrachloro-2-cyclotriphos-phazenyl)phosphine-P](triphenyl phosphite-P)manganese(I) hexafluorophosphate, [Mn(C18H15O3P)(C10H8N2)(C18H15Cl4N3P4)(CO)(2)]PF6, consists of discrete complex cations and PF6- anions linked by several weak C-H...O and C-H...F interactions. The cation is a very distorted octahedral manganese-dicarbonyl fragment having cis-trans stereochemistry and bearing triphenylphosphite, bipyridine and phosphazenylphosphine [N3P3Cl4(Ph)(PPh(2))] ligands. Analysis of the structure of the complex reveals that the coordination of the phosphazenylphosphine ligand to the cationic manganese-carbonyl fragment induces only minor changes in the phosphazene ring, affecting only the P5-P3 bond length.