| 167114-47-8

• CAS: 167114-47-8
• 化学式: C₁₈H₂₇GaN₂O
• 分子量: 357.148
• InChiKey: CEMCMGLUFAJCAV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-苄氨基吡啶 、 乙醚 、 甲基锂 、 氯化镓 以 乙醚 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  镓和铟的五坐标有机​​金属配合物

  摘要：

  Using 2-benzylaminopyridine anion as a ligand, we have prepared a family of five- and six-coordinate organometallic complexes of Ga-III and In-III The monomeric nature and unusual distorted square-based pyramidal coordination geometries of the metal centers for M{2-[N(CH2C6H5)]NC5H4}(2)Me (M = Ga, 1; M = In, 2) were confirmed through single-crystal X-ray diffraction analyses. An intermediate in the formation of the gallium complex, Ga{2-[N(CH2C6H5)]NC5H4}Me(2)(OEt(2)), has been characterized spectroscopically. Further reaction of 2 with a third equivalent of amine yields a six-coordinate tris-ligand complex, {2-[N(CH2C6H5)]NC5H4}In-3.

  DOI：

  10.1021/om00007a064