| 1335098-15-1

• CAS: 1335098-15-1
• 化学式: C₂₆H₂₆Br₄N₂Pd₂Se₂
• 分子量: 1056.88
• InChiKey: ARZWNTMCJYEVGL-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(phenyl-selenomethyl)-6-methyl-pyridine 、 palladium(II) bromide 以 乙腈 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Structural chemistry of dihalogenopalladium(II) and platinum(II) complexes of heteroleptic N,S- and N,Se-donor ligands based on the 2-organochalcogenomethylpyridine motif

  摘要：

  The structural chemistry of dihalogenopalladium(II) and platinum(II) complexes of 2-organochalcogenomethylpyridine ligands is described. Complexes with a methyl group in the 6-position of the pyridyl ring, 6-MepyCH(2)ER, form dimeric complexes [trans-PdX2(mu-6-MepyCH(2)SePh-N,Se)](2) (X = Br (1), I (2)) or mononuclear complexes trans-PdI2(6-MepyCH(2)SR-N)(2) (R = Me (5), Ph (6)). Absence of a 6-methyl substituent results in the bidentate configuration observed for PdI2(pyCH(2)SePh-N,Se) (3) and PdI2(4-MepyCH(2)SMeN, S) (4). Related platinum(II) complexes are mononuclear including PtCl2(6-MepyCH(2)SPh-N,S) (8) as an analogue of trimeric [trans-PdCl2(mu-6-MepyCH(2)SPh-N,S)](3). Differences between palladium and platinum appear to result from a combination of steric and electronic factors. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.06.032