di-μ-chlorido-bis[chlorido(4'-p-tolyl-2,2':6',2''-terpyridine-κ3N,N',N'')nickel(II)] | 1226614-54-5

• 英文名称: di-μ-chlorido-bis[chlorido(4'-p-tolyl-2,2':6',2''-terpyridine-κ3N,N',N'')nickel(II)]
• CAS: 1226614-54-5
• 化学式: C₄₄H₃₄Cl₄N₆Ni₂
• 分子量: 905.986
• InChiKey: NTXVJIZECQUJFC-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 4′-(4-甲基苯基)-2,2′:6′,2′′-三吡啶 以 乙醇 为溶剂， 生成 di-μ-chlorido-bis[chlorido(4'-p-tolyl-2,2':6',2''-terpyridine-κ3N,N',N'')nickel(II)]
  参考文献：
  名称：

  Di-μ-chlorido-bis[chlorido(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ³N,N′,N′′)nickel(II)]: a supramolecular system constructed by C—H...Cl interactions

  摘要：

  The title complex, [Ni2Cl4(C22H17N3)(2)], was synthesized solvothermally. The molecule is a centrosymmetric dimer with the unique Ni-II centre in a distorted octahedral N3Cl3 coordination environment. The chloride bridges are highly asymmetric. In the 4'-p-tolyl-2,2':6',2 ''-terpyridine ligand, the p-tolyl group is perfectly coplanar with the attached pyridine ring, and this differs from the situation found in previously reported compounds; however, there are no pi-pi interactions between the ligands. The terminal Cl atom forms four intermolecular C-H center dot center dot center dot Cl hydrogen bonds with one methyl and three methine groups. The methyl group also forms intermolecular C-H center dot center dot center dot pi interactions with a pyridine ring. These nonclassical hydrogen bonds extend the molecule into a three-dimensional network.

  DOI：

  10.1107/s0108270109018812