[(η5-C5Me5)Rh(CO)(CH3CO)(dimethylphenylphosphine)](BF4) | 817628-73-2

• 英文名称: [(η5-C5Me5)Rh(CO)(CH3CO)(dimethylphenylphosphine)](BF4)
• CAS: 817628-73-2
• 化学式: BF₄*C₂₁H₂₉O₂PRh
• 分子量: 534.144
• InChiKey: MMFIEUXHPBXUDC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(η5-C5Me5)RhMe(CO)2](BF4) 、 二甲基苯基磷 以 二氯甲烷 为溶剂， 生成 [(η5-C5Me5)Rh(CO)(CH3CO)(dimethylphenylphosphine)](BF4)
  参考文献：
  名称：

  Facile Alkene Insertion into a Rhodium(III)−Acetyl Bond:  Potential Catalysts for CO/Alkene Copolymerization

  摘要：

  Cationic Rh(III) methyl complexes, [(eta(5)-ligand)-Rh(CO)(2)Me](+) (eta(5)-ligand = C5Me5, C9Me7, C9Me3H4), undergo facile reactions with strained alkenes (e.g. norbornadiene) to give products resulting from insertion of the alkene into a Rh-acetyl bond. Kinetic, mechanistic, and structural results are presented, along with evidence of catalytic activity for CO/alkene copolymerization.

  DOI：

  10.1021/om049258e