| 686333-92-6

• CAS: 686333-92-6
• 化学式: C₃₂H₃₂Cl₂N₄O₂Pd
• 分子量: 681.958
• InChiKey: QSYWRYSMZYEDBK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二(氰基苯)二氯化钯 、 N-methyl-4-tolylnitrone 以 苯甲腈 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Reactions of nitrones with transition metal nitrile complexes: cycloaddition, ligand substitution, or hydrolysis

  摘要：

  The reaction of nitrones with transition metal nitrile complexes of the type [MCl2(PhCN)(2)] and [MCl4(MeCN)(2)] leads to different products, depending on the metal. Reaction of [PdCl2(PhCN)(2)] with RCH=N(Me)O (R=Ph, p-C6H4Me) afford Delta(4)-1,2,4-oxadiazoline complexes [PdCl2{N=C(Ph)O-N(Mc)CH(R)}(2)] as products of [2+3] cycloaddition of the nitrone across the Cequivalent toN bond of the nitrile. The oxophilic transition metal compounds [TiCl4(MeCN)(2)] and [ZrCl4(MeCN)(2)] undergo rapid ligand exchange to form nitrone complexes from which the nitrone can be released without decomposition. The closely related compounds [MoCl4(MeCN)(2)] and [WCl4(MeCN)(2)] mediate the hydrolysis of nitrones to the corresponding aldehydes. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.10.007