[Re(picolinate)(N2)(CO)(PPh3)2] | 911682-41-2

• 英文名称: [Re(picolinate)(N2)(CO)(PPh3)2]
• CAS: 911682-41-2
• 化学式: C₄₃H₃₄N₃O₃P₂Re
• 分子量: 888.916
• InChiKey: OAWUCBQYHSMTKJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-吡啶甲酸 、 [ReCl(dinitrogen)(carbon monoxide)2(triphenylphosphane)2] 以 甲醇 、 苯 为溶剂， 以65%的产率得到[Re(picolinate)(N2)(CO)(PPh3)2]
  参考文献：
  名称：

  A picolinate-N2 complex of rhenium, the first dinitrogen complex bearing a carboxylate or a N,O-ligand

  摘要：

  A new dinitrogen rhenium(I) complex with a picolinate ligand has been prepared and fully characterized, providing the first example of a genuine N N complex bearing a carboxylate or a N,O-coligand. The Lever electrochemical E-L ligand parameter was estimated for the first time for the picolinate ligand and shows that its carboxylate arm has a net electron-donor character similar to that of chloride, thus stabilizing the trans Re-N-2 bond. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.06.015