[Ru3(CO)8(1,2-bis(bis-pentafluorophenylphosphino)ethane)2] | 390809-80-0

• 英文名称: [Ru3(CO)8(1,2-bis(bis-pentafluorophenylphosphino)ethane)2]
• CAS: 390809-80-0
• 化学式: C₆₀H₈F₄₀O₈P₄Ru₃
• 分子量: 2043.76
• InChiKey: FNDSGYSHVVQQHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十二羰基三钌 、 1,2-双(二五氟代苯基磷基)-乙烷 以 四氢呋喃 为溶剂， 以36%的产率得到Ru3(CO)10(1,2-bis(bis-pentafluorophenylphosphino)ethane)
  参考文献：
  名称：

  New Ru3(CO)12 derivatives with bulky diphosphine ligands: synthesis, structure and catalytic potential for olefin hydroformylation

  摘要：

  The diphosphine clusters Ru-3(CO)(10)(dcpm) (1) and Ru-3(CO)(10)(F-dppe) (2) as well as the bis(diphosphine) clusters Ru-3(CO)(8)(dcpm)(2) (3) and Ru-3(CO)(8)(F-dppe)(2) (4) have been synthesised from Ru-3(CO)(12) and the bulky diphosphines 1,2-bis[bis(pentafluorophenyl)phosphino]ethane (F-dppe) and bis(dicyclohexylphosphino)methane (dcpm). While the single-crystal X-ray structure analyses of 1, 2 and 3 show the expected mu (2)-eta (2) coordination of the diphosphine ligands, that of 4 reveals an unusual structure with one mu (2)-eta (2)-diphosphine and one mu (1)-eta (2)-diphosphine ligand. The clusters 1-4 catalyse the hydroformylation of ethylene and propylene to give the corresponding aldehydes, 2 showing higher activities than those observed for Ru-3(CO)(12) and Ru-3(CO)(10)(dppc). (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00863-4