| 335194-33-7

• CAS: 335194-33-7
• 化学式: C₂₃H₃₃Cl₂NO₂RuTe
• 分子量: 655.097
• InChiKey: ODRHUFCNMDQBCR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二氯(p-甲基异丙苯)钌(II) 二聚体 、 N-(2-(4-methoxyphenyltelluro)ethyl)morpholine 以 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  N-{2-(4-methoxyphenyltelluro)ethyl}morpholine (L1) and its platinum(II) and ruthenium(II) complexes. Synthesis and crystal structure of L1 and trans-[PtCl2(L1)2]

  摘要：

  The first tellurated derivative of morpholine, N-{2-(4-methoxyphenyltelluro)ethyl}morpholine (L-1) has been synthesized by reacting in situ generated ArTe- with 4-(2-chloroethyl)morpholine hydrochloride under N-2 atmosphere. The compound L-1 gives molecular ion peak at m/z 351 and is characterized structurally. The donor atoms N and Te in compound L-1 are rightly oriented for its ligation in bidentate mode. The Te-C(alkyl) is 0.02 Angstrom longer than Te-C(aryl). The complexes of ligand L-1 having composition [PtCl2(L-1)(2)] (1) and [RuCl2(p-cymene)L-1] (2) have been synthesized. The compound 1 has been characterized structurally. The Pt has a square planar geometry in complex 1 and two molecules of ligand L-1 bonded through Te alone are trans to each other (Pt-Te = 2.583(2) Angstrom). The C-13{H-1} NMR spectrum of complex 1 is as expected. The H-1 NMR spectrum of single crystals of complex 1 shows multiplication of signals, which is supported by HETCOR experiments. The complex 2 also has ligand L-1 in a monodentate coordination mode, bonded through Te alone. This is supported by deshielded CH2Te and ArC-Te signals in H-1 and C-13{H-1} NMR spectra of complex 2 with respect to those of free ligand L-1. The HETCOR spectrum of complex 2 has been used to authenticate the assignments of CH2Te group, as its two protons appear to be magnetically non-equivalent. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00355-8