[GaCl3(2,6-(2,4,6-iPr3C6H2)2C5H3N)] | 1210109-72-0

• 英文名称: [GaCl3(2,6-(2,4,6-iPr3C6H2)2C5H3N)]
• CAS: 1210109-72-0
• 化学式: C₃₅H₄₉Cl₃GaN
• 分子量: 659.863
• InChiKey: FFSIDOFTXKTCTL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,6-bis(2,4,6-triisopropylphenyl)pyridine 、 氯化镓 以 甲苯 为溶剂， 以75%的产率得到[GaCl3(2,6-(2,4,6-iPr3C6H2)2C5H3N)]
  参考文献：
  名称：

  Gallium tri-chloride derivatives of the sterically demanding pyridines 2,6-Ar2C6H3N (Ar=2,4,6-Me3C6H2 or 2,4,6-Pri3C6H2)

  摘要：

  The sterically demanding pyridines 2,6-Ar2C6H3N [Ar = 2,4,6-Me3C6H2 (1) or 2,4,6-(Pr3C6H2)-C-i (2)] were prepared by a palladium catalysed Kumada C-C coupling reaction in high yield. Pyridine I reacted with one equivalent of GaCl3 to afford the tetra-chloro gallate-pyridinium ion pair complex [GaCl4](-)[2,6-(2,4,6-Me3C6H2)(2)C6H3NH](+) (3). Contrastingly, pyridine 2 reacted with one equivalent of GaCl3 to afford the anticipated donor-acceptor complex [GaCl3{2,6-(2,4,6-(Pr3C6H2)-C-i)(2)C6H3N}] (4). Complexes 1-4 have been characterised variously by single crystal X-ray diffraction, NMR, CHN, and mass spectrometry. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.06.011