Reaction of [Os3(CO)10(NCMe)2] with amides and aldehydes; X-ray crystal structure of [Os3(CO)10(μ-H)(COCH2Ph)]
作者:Brian F.G. Johnson、Jack Lewis、Timothy L. Odiaka、Paul R. Raithby
DOI:10.1016/s0022-328x(00)85827-1
日期:1981.8
Reaction of [OS3(CO)10(NCMe)2] with amides and aldehydes has provided a high-yield route to clusters of the type [OS3(CO)10H(NHCOR)] (R H, Me, Ph, Et, Pr) and [OS3(CO)10H(COR)] (R Me, Ph, CH2Ph, C6H13), respectively; the molecular structure of [OS3(CO)10H(COCH2Ph)] has been established by a single-crystal X-ray analysis.
[OS 3(CO)10(NCMe)2 ]与酰胺和醛的反应为[OS 3(CO)10 H(NHCOR)]类型的簇提供了高收率的途径(R H,Me,Ph ,Et,Pr)和[OS 3(CO)10 H(COR)](RMe,Ph,CH 2 Ph,C 6 H 13)分别;[OS 3(CO)10 H(COCH 2 Ph)]的分子结构已通过单晶X射线分析确定。