1-acetyl-5-ferrocenyl-3-(2-pyridyl)-pyrazole | 944395-90-8

• 英文名称: 1-acetyl-5-ferrocenyl-3-(2-pyridyl)-pyrazole
• CAS: 944395-90-8
• 化学式: C₂₀H₁₇FeN₃O
• 分子量: 371.221
• InChiKey: FNZLTHNXRTWYSZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  5-ferrocenyl-3-(2-pyridyl)-1H-pyrazole 、 乙酰氯 在 (C₂H₅)3N 作用下， 以 四氢呋喃 为溶剂， 以47.2%的产率得到1-acetyl-5-ferrocenyl-3-(2-pyridyl)-pyrazole
  参考文献：
  名称：

  1-Acetyl-3-ferrocenyl-5-methyl-1H-pyrazole and 1-acetyl-5-ferrocenyl-3-(2-pyridyl)-1H-pyrazole

  摘要：

  Molecules of 1-acetyl-3-ferrocenyl-5-methyl-1H-pyrazole, [Fe(C5H5)(C11H11N2O)], form a centrosymmetric dimer generated by a combination of one C-H center dot center dot center dot pi (pyrazole) and one C-H center dot center dot center dot pi (cyclopentadienyl) interaction. The dimers are linked by C-H center dot center dot center dot pi interactions, involving the pyrazole rings as acceptors, into layers parallel to ( 101). Molecules of 1-acetyl-5-ferrocenyl-3-(2-pyridyl)-1H-pyrazole, [Fe(C5H5)(C15H12N3O)], are linked by C-H center dot center dot center dot O interactions into a chain running in the [ 010] direction. Two chains of this type passing through each unit cell are connected by C-H center dot center dot center dot pi (pyridyl) interactions into an [ 010] double chain.

  DOI：

  10.1107/s0108270106043599