| 268543-80-2

• CAS: 268543-80-2
• 化学式: C₃₆H₅₆Al₂Cl₂N₂O₂
• 分子量: 673.722
• InChiKey: WVGIYCAZZDCXPT-CSGKTOEJSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二甲基氯化铝 、 N,N'-bis(3,5-di-tert-butylsalicylidene)-1,4-diaminobutane 以 甲苯 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Bimetallic Aluminum and Gallium Chelates with N₂O₂ Ligands

  摘要：

  A wide range of bimetallic aluminum molecules are formed in combinations between Salen Schiff base ligands and either AlR3 or AlR2Cl. They are of the general formulas L(AlR2)(2) and L(AlRCl)(2) with R = alkyl and L = Salen(Bu-t) ligand with relatively unusual "backbone" connections between the nitrogen atoms, 1,2-cyclohexylene (Salcen(Bu-t)), 1,4-butylene (Salben(Bu-t)), 1,5-pentylene (Salpten(Bu-t)), 1,6-hexylene (Salhen(Bu-t)), and 1,4-phenylene (1,4-Salophen(Bu-t)). Additionally, previously unknown ligands were employed with the "backbones" 1,4-bis(p-aminobenzyl)benzene (Salmaben(Bu-t)), 1-(m-aminobenzoyl)-4-(m-aminobenzyl)benzene (Salmabmaben(Bu-t)), and 4,4'-bis(m-aminobenzoyl)diphenylmethane (Salmadmen(Bu-t)). The ligands for these compounds were designed to feature two group 13 sites at long and varying distances from one another. The compounds were characterized by mp analyses, IF, and H-1 NMR, and X-ray structures were determined for the examples R,R'-Salcen(Bu-t){AlMe2}(2) (1), Salben(Bu-t){AlMe2}(2) (2), 1,4-Salophen(Bu-t){GaEt2}(2) (7), R,R'-Salcen(Bu-t){AlMe2}(2) (11), Salben(Bu-t){AlMeCl}(2) (13), and Salhen(Bu-t){AlMeCl}(2) (14).

  DOI：

  10.1021/om990829q