[CuCl(2,6-[1-(2,6-diisopropylphenylimino)ethyl]pyridine)(C10N7)]*methylisobutylketone | 852528-84-8

• 英文名称: [CuCl(2,6-[1-(2,6-diisopropylphenylimino)ethyl]pyridine)(C10N7)]*methylisobutylketone
• CAS: 852528-84-8
• 化学式: C₆H₁₂O*C₁₀N₇*C₃₃H₄₃ClCuN₃
• 分子量: 899.041
• InChiKey: ASAKTPIWMVUKQS-VRCYMSAESA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [CuBr(2,6-[1-(2,6-diisopropylphenylimino)ethyl]pyridine)]PF6 、 tetraethylammonium 1,1,2,4,5,5-hexacyano-3-azapentadienide 、 4-甲基-2-戊酮 以 丙酮 为溶剂， 以75%的产率得到[CuCl(2,6-[1-(2,6-diisopropylphenylimino)ethyl]pyridine)(C10N7)]*methylisobutylketone
  参考文献：
  名称：

  Organocyanide coordination chemistry: Syntheses, structural characterisations and magnetic properties of copper (II) complexes with a di-imine/pyridine ligand

  摘要：

  The reactions between the copper (11) salts [CuXL]PF6 (L: 2,6-[1-(2,6-d iisopropylphenylimino)ethyl]pyridine) (X = Cl 1, X = Br 2) and LiTCNQ, in a DMF/water mixture, or Et3NH(TCNQ)(2), in acetone, produced the new complexes [CuXL(TCNQ)] (X = Cl 3, X = Br 4). For both compounds, crystallographic studies have clearly evidenced the existence of dimeric complexes [{CuClL}(TCNQ)](2) owing to pi-pi overlap between two adjacent TCNQ(center dot-) radical anions. Compound 1 reacted with Et4N(C10N7) to afford the mononuclear derivative [CuC1L(C10N7)] (5), while its reaction with K2C10N6 produced the dinuclear complex [(CuClL)(2)(C10N6)] (6). The crystal structures of complexes 5 and 6 have been determined by X-ray crystallography. Magnetic studies have revealed that compound 6 displays weak antiferromagnetic interactions between the two metal centres, conversely compounds 3 and 5 exhibit purely paramagnetic behaviours. (c) 2005 Elsevier B.V.. All rights reserved.

  DOI：

  10.1016/j.ica.2005.02.011