bis(1,5-diselena[5]ferrocenophane)silver(I) hexafluorophosphate | 1207685-19-5

• 英文名称: bis(1,5-diselena[5]ferrocenophane)silver(I) hexafluorophosphate
• CAS: 1207685-19-5
• 化学式: C₂₆H₂₈AgFe₂Se₄*F₆P
• 分子量: 1020.87
• InChiKey: UBPOWBXSOAQPSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  六氟磷酸银 、 1,5-diselena[5]ferrocenophane 以 四氢呋喃 为溶剂， 以35%的产率得到bis(1,5-diselena[5]ferrocenophane)silver(I) hexafluorophosphate
  参考文献：
  名称：

  Complexation and electrochemical study of 1,5-diselena[5]ferrocenophane: X-ray crystal structures of 1,5-diselena[5]ferrocenophane, and silver, mercury complexes

  摘要：

  The silver(I) and mercury(II) complexes of 1,5-diselena[5]ferrocenophane (L) have been synthesized. The X-ray crystal structures of L. [AgL2]PF6 and [Hgl(2)L] are reported. The small cavity of the macrocyclic ligand means that the ring must undergo a conformational change to allow coordination, and there is no significant through-space interaction M center dot center dot center dot Fe in any of the complexes. Electrochemical studies showed that no electronic communication between ferrocenylene groups was observed in the silver complex where the through-bond Fe center dot center dot center dot Fe distances are in the range 13.10 (3)-13.27(3) angstrom. (c) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2009.03.008