cis-[C6H4C(O)NMePNEt2NCH2]PtCl2 | 300352-83-4

• 英文名称: cis-[C6H4C(O)NMePNEt2NCH2]PtCl2
• CAS: 300352-83-4
• 化学式: C₂₆H₃₈Cl₂N₆O₂P₂Pt
• 分子量: 794.56
• InChiKey: XVHGAAYJALQAIA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氘代氯仿 、 cis-[C6H4C(O)NMePNEt2NCH2]PtCl2 以 乙醚 、 氘代氯仿 为溶剂， 生成 cis-[C6H4C(O)NMePNEt2NCH2]PtCl2*2CDCl3
  参考文献：
  名称：

  摘要：

  The reaction of the bis-chlorophosphines 1a-1d with bis(2-chloroethyl)amine hydrochloride in the presence of triethylamine and with various trimethylsilylamines led to a new class of his-phosphorus ligands 2a-2c and 3a-3g. P-31- NMR studies suggested that the bis-phosphorus ligands undergo rotation reactions about the alkyl bridge in polar solvents. Compounds 2a-2c showed initially only one sharp singlet each in their P-31-NMR spectra. After a few days at room temperature, two signals were observed. Similar results were observed for 3a-3g. In the solid state, the two phosphorus atoms in 2c are not equivalent, as was confirmed by the observation of two signals in the solid state P-31-NMR spectrum. Oxidation reactions of 2a-2c by the hydrogen peroxide-urea 1:1 adduct (NH2)(2)C(:O) . H2O2 led to the formation of the corresponding phosphoryl compounds 4a-4c. Reaction of 2a and 3a with Pt[COD]Cl-2 (COD = 1.5-Cyclooctadiene) furnished the complexes 5 and 6. The NMR spectra suggested that the two chlorine atoms are in cis position. X-ray structure analyses were conducted for 2a, which exhibits twofold symmetry; 2c, which is linked into dimers by hydrogen bonds C-H ... O; and 6, confirming the cis configuration.

  DOI：

  10.1002/1521-3749(200008)626:8<1763::aid-zaac1763>3.0.co;2-u
• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 3,3'-(ethane-1,2-diyl)bis(2-(diethylamino)-1-methyl-2,3-dihydrobenzo[d][1,3,2]diazaphosphinin-4(1H)-one) 以 二氯甲烷 为溶剂， 以69%的产率得到cis-[C6H4C(O)NMePNEt2NCH2]PtCl2
  参考文献：
  名称：

  摘要：

  The reaction of the bis-chlorophosphines 1a-1d with bis(2-chloroethyl)amine hydrochloride in the presence of triethylamine and with various trimethylsilylamines led to a new class of his-phosphorus ligands 2a-2c and 3a-3g. P-31- NMR studies suggested that the bis-phosphorus ligands undergo rotation reactions about the alkyl bridge in polar solvents. Compounds 2a-2c showed initially only one sharp singlet each in their P-31-NMR spectra. After a few days at room temperature, two signals were observed. Similar results were observed for 3a-3g. In the solid state, the two phosphorus atoms in 2c are not equivalent, as was confirmed by the observation of two signals in the solid state P-31-NMR spectrum. Oxidation reactions of 2a-2c by the hydrogen peroxide-urea 1:1 adduct (NH2)(2)C(:O) . H2O2 led to the formation of the corresponding phosphoryl compounds 4a-4c. Reaction of 2a and 3a with Pt[COD]Cl-2 (COD = 1.5-Cyclooctadiene) furnished the complexes 5 and 6. The NMR spectra suggested that the two chlorine atoms are in cis position. X-ray structure analyses were conducted for 2a, which exhibits twofold symmetry; 2c, which is linked into dimers by hydrogen bonds C-H ... O; and 6, confirming the cis configuration.

  DOI：

  10.1002/1521-3749(200008)626:8<1763::aid-zaac1763>3.0.co;2-u