Zn(4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane)Cl2 | 588690-60-2

• 英文名称: Zn(4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane)Cl2
• CAS: 588690-60-2
• 化学式: C₁₂H₂₆Cl₂N₄Zn
• 分子量: 362.661
• InChiKey: ZMXGSYHSMBWHJY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetraadecane 、 zinc(II) chloride 以 乙腈 为溶剂， 以80%的产率得到Zn(4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane)Cl2
  参考文献：
  名称：

  Synthesis, structure, and stability in acid of copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocycles

  摘要：

  New copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocyclic ligands derived from 1,4,8,11-tetraazacyclotetradecane (cyclam), 1,4,7,10-tetraazacyclotridecane([13]aneN4), and 1,4,7,10-tetraazacyclododecane (cyclen) have been synthesized. The X-ray crystal structures of the two cyclen-derived complexes have been determined and show both metal ions to be in distorted octahedral environments with the ligand in a cis-folded conformation. The bridged-ligand complexes are remarkably stable kinetically under harsh acidic conditions, as seen from their dissociation reactions. The electrochemical and spectroscopic properties of the Cu2+ complexes have also been investigated. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(03)00036-7