[Yb(C5Me5)(C6F5)(THF)3] | 516471-39-9

• 英文名称: [Yb(C5Me5)(C6F5)(THF)3]
• CAS: 516471-39-9
• 化学式: C₂₈H₃₉F₅O₃Yb
• 分子量: 691.648
• InChiKey: YEZTXKRWKGJINU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四氢呋喃 、 pentafluorophenyl(phenyl)mercury 、 1,2,3,4,5-五甲基环戊二烯 、 氢化镱 以 四氢呋喃 为溶剂， 以41%的产率得到[Yb(C5Me5)(C6F5)(THF)3]
  参考文献：
  名称：

  A Half-Sandwich Perfluoroorganoytterbium(II) Complex from a Simple Redox Transmetalation/Ligand Exchange Synthesis

  摘要：

  Reaction of ytterbium metal with HgPh(C6F5) and HC5Me5 in THF (THF = tetrahydrofuran) affords seven-coordinate, monomeric [Yb(C5Me5)(C6F5)(THF)(3)] (1), which is presumed to be formed by protolysis of a transitory "YbPh(C6F5)" species with HC5Me5. In the absence of the latter, reaction of ytterbium metal and HgPh(C6F5) gave a mixture of products, including the structurally characterized [Yb(C6F5)(2)(THF)(4)] (2) and the ytterbium(III) complex [YbPh3(THF)(3)] (3).

  DOI：

  10.1021/om021039a