trans-[RuCl2(bis(3,5-dimethylpyrazol-1-yl)methane)2](1+) | 1123208-21-8

• 英文名称: trans-[RuCl2(bis(3,5-dimethylpyrazol-1-yl)methane)2](1+)
• CAS: 1123208-21-8
• 化学式: C₂₂H₃₂Cl₂N₈Ru
• 分子量: 580.526
• InChiKey: LLZDXMKABFKXGP-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  trans-[RuCl2(bis(3,5-dimethylpyrazol-1-yl)methane)2](1+) 以 乙腈 为溶剂， 生成 trans-[RuCl2(bis(3,5-dimethylpyrazol-1-yl)methane)2]
  参考文献：
  名称：

  trans-[RuIII(N-N)2Cl2]+ species, where N-N is bis(3,5-dimethylpyrazol-1-yl)methane

  摘要：

  Using bis(3,5-dimethylpyrazol-1-yl)methane as an N-N donor ligand, a trans-[Ru-III(N-N)(2)Cl-2](+) core has been isolated from the direct reaction of the ligand with RuCl3 center dot xH(2)O and characterized structurally for the. first time. The core displays a rhombic EPR spectrum and a quasireversible Ru(II/III) couple with an E-1/2 of -0.34 V versus NHE. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.04.004