[Ir(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl | 191590-22-4

• 英文名称: [Ir(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl
• CAS: 191590-22-4
• 化学式: C₃₂H₂₈Cl₂IrN₄*Cl
• 分子量: 767.18
• InChiKey: VJZLGALVRCKAHC-GEMMDNRXSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三氯化铱 、 2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene 以 乙醇 为溶剂， 以72%的产率得到[Ir(2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene)(Cl)2]Cl
  参考文献：
  名称：

  Synthesis and Spectral Studies of Platinum Group Metal Complexes of three Twelve-Membered Tetradentate Macrocyclic Ligands

  摘要：

  Platinum group metal complexes of the general compositions M(Ligand)Cl-3 [M = Ru(III), Ir(III)] and M(Ligand)Cl-2 [M = Pd(II), Pt(II) have been synthesized [Ligand = 2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene (L-1), dibenzo[e,k]-2,3,8,9-tetraphenyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene (L-2) and dibenzo[e,k]-2,3,8,9-tetramethyl-1,4,7,10-tetraazacyclododeca-1,3,7,9-tetraene (L-3)]. The complexes have been characterized on the basis of elemental analyses, molar conductance, magnetic susceptibility measurements and electronic spectral studies. Sharp bands were observed in the electronic spectra of the complexes. The epsilon values could not be reported as the spectra and been recorded in Nujol mulls. The Ru(III) and Ir(III) complexes have been found to stabilize an octahedral geometry while a square-planar geometry is assigned to the Pd(II) and Pt(II) complexes.

  DOI：

  10.1080/00945719708000220