2,2'-bis(ethynyl-ferrocenyl)propane | 917500-96-0

• 英文名称: 2,2'-bis(ethynyl-ferrocenyl)propane
• CAS: 917500-96-0
• 化学式: C₂₇H₂₄Fe₂
• 分子量: 460.182
• InChiKey: AHZZDNBZEFLSEI-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 2,2'-bis(ethynyl-ferrocenyl)propane 以 苯 为溶剂， 以74%的产率得到2,2'-bis(Co2(CO)6-ethynyl-ferrocenyl)propane
  参考文献：
  名称：

  Studies on the synthesis of novel 2,2′-bis(ferrocenyl)propane derivatives and their reactivity with metal carbonyl clusters

  摘要：

  The reaction of new ferrocenylacetylene HC=C(C5H5FeC5H3)C(CH3)(2)Fc'C=CH (1; Fc'=C5H4FeC5H4) with Co-2(CO)(8) has been studied and the spectra and molecular structure of complexes [HC=C(C5H5FeC5H3)C(CH3)2Fc'C=CH][Co-2(CO)(6)](n) [n = 1, (4); n = 2, (5)] have been determined. Novel complex [FcC(CH3)(2)FcCH=C]FeCo2(CO)(9) (6; Fc = C5H5FeC5H4) has been synthesized by using a nuclear expanding reaction of complex [FcC(CH3)(2)Fc'=CH]Co-2(CO)(6) (3) with Fe-2(CO)(9) and the structural characterization of complex 6 was accomplished by elemental analysis, IR, H-1, C-13 NMR and MS. The electrochemical properties of the compounds with ferrocenylacetylene reveal that there is significant electronic communication between the ferrocenyl groups. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.05.022
• 作为产物：
  描述：

  2,2'-bis(CH2CCl-ferrocenyl)propane 在 NaOH 、 HCl 作用下， 以 1,4-二氧六环 为溶剂， 生成 2,2'-bis(ethynyl-ferrocenyl)propane
  参考文献：
  名称：

  Studies on the synthesis of novel 2,2′-bis(ferrocenyl)propane derivatives and their reactivity with metal carbonyl clusters

  摘要：

  The reaction of new ferrocenylacetylene HC=C(C5H5FeC5H3)C(CH3)(2)Fc'C=CH (1; Fc'=C5H4FeC5H4) with Co-2(CO)(8) has been studied and the spectra and molecular structure of complexes [HC=C(C5H5FeC5H3)C(CH3)2Fc'C=CH][Co-2(CO)(6)](n) [n = 1, (4); n = 2, (5)] have been determined. Novel complex [FcC(CH3)(2)FcCH=C]FeCo2(CO)(9) (6; Fc = C5H5FeC5H4) has been synthesized by using a nuclear expanding reaction of complex [FcC(CH3)(2)Fc'=CH]Co-2(CO)(6) (3) with Fe-2(CO)(9) and the structural characterization of complex 6 was accomplished by elemental analysis, IR, H-1, C-13 NMR and MS. The electrochemical properties of the compounds with ferrocenylacetylene reveal that there is significant electronic communication between the ferrocenyl groups. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.05.022