(2,4,6-triethylphenylcopper)4 | 891760-10-4

• 英文名称: (2,4,6-triethylphenylcopper)4
• CAS: 891760-10-4
• 化学式: C₄₈H₆₈Cu₄
• 分子量: 899.252
• InChiKey: VKDLHGPLJJQSFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1-溴-2,4,6-三乙基苯 、 copper(l) chloride 在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以70%的产率得到(2,4,6-triethylphenylcopper)4
  参考文献：
  名称：

  Tetranuclear homoleptic copper and silver aryls: 2,4,6-Triethylphenylcopper and 2,4,6-triethylphenylsilver

  摘要：

  The ethyl analogues of mesityleopper and mesitylsilver, 2,4,6-triethylphenylcopper and 2,4,6-triethylphenylsilver, have been prepared and characterised by means of crystal structure determination. Three different compounds, [Cu-4(Et3Ph)(4)] center dot 2C(6)H(5)CH(3) (1), [Cu-4(Et3Ph)(4)]center dot 1/2(C2H5)(2)O (2) and [Ag-4(Et3Ph)(4)] center dot 1/2C(6)H(5)CH(3) (3), have thus been obtained by crystallisation from toluene or diethylether/tetrahydrofuran. All three show the square-planar metal core, most characteristic of homoleptic copper and silver aryls. The ordered (1) or disordered (2 and 3) solvent molecules are situated in the channels formed between the organometallic complexes, there being no strong directional interactions between the solvent and 2,4,6-triethylphenyleopper or 2,4,6-triethylphenylsilver. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.02.024