| 191288-19-4

• CAS: 191288-19-4
• 化学式: C₁₆H₁₄Br₂Cl₂N₂O₂Pd₂
• 分子量: 709.853
• InChiKey: LHSUJSHIPCUCQW-OIJLIKNUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三苯基膦 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of cyclopalladated complexes of oximes by ligand-exchange method

  摘要：

  The ligand-exchange reaction between {Pd(dmba)Cl}(2) (dmba = N,N-dimethylbenzylamine) and various oximes such as 3,4-(Me)(2)C6H3C(CH3)=NOH (1), 4-OMeC6H4C(CH3)-NOH (2), 4-BrC6H4C(CH3) =NOH (3) and alpha-tetrarone oxime (4) was studied. The products obtained were found to he chloro-bridged complexes. The reactions of these complexes were investigated with triphenylphosphine and acetylacetone. The resulting complexes were analysed by IR, H-1 NMR and C-13 NMR methods. For one of the complexes, [{Pd(4,5-(CH3)(2)C6H2C(CH3)=NOH)(Cl)}(2)] (1a), the structure was investigated by single crystal XRD. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00535-9
• 作为产物：
  描述：

  p-bromoacetophenone oxime 、 bis[(benzyldimethylamino)chloropalladium(II)] 以 氯仿 、 溶剂黄146 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and characterization of cyclopalladated complexes of oximes by ligand-exchange method

  摘要：

  The ligand-exchange reaction between {Pd(dmba)Cl}(2) (dmba = N,N-dimethylbenzylamine) and various oximes such as 3,4-(Me)(2)C6H3C(CH3)=NOH (1), 4-OMeC6H4C(CH3)-NOH (2), 4-BrC6H4C(CH3) =NOH (3) and alpha-tetrarone oxime (4) was studied. The products obtained were found to he chloro-bridged complexes. The reactions of these complexes were investigated with triphenylphosphine and acetylacetone. The resulting complexes were analysed by IR, H-1 NMR and C-13 NMR methods. For one of the complexes, [{Pd(4,5-(CH3)(2)C6H2C(CH3)=NOH)(Cl)}(2)] (1a), the structure was investigated by single crystal XRD. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00535-9