1,1-dichloro-1-(2-(diphenylphosphaneyl)benzyl)-N,N-dimethyl-l4-boranamine | 193821-34-0

• 英文名称: 1,1-dichloro-1-(2-(diphenylphosphaneyl)benzyl)-N,N-dimethyl-l4-boranamine
• CAS: 193821-34-0
• 化学式: C₂₁H₂₃BCl₂NP
• 分子量: 402.111
• InChiKey: QTDQPCLKGUIFPG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  以 四氢呋喃 、 乙醚 、 正己烷 、 甲苯 为溶剂， 生成 1,1-dichloro-1-(2-(diphenylphosphaneyl)benzyl)-N,N-dimethyl-l4-boranamine
  参考文献：
  名称：

  Synthesis and reactions of {o-{[bis(dimethylamino)boryl]methyl}phenyl}diphenylphosphane

  摘要：

  AbstractThe new α,ω‐[boryl(organyl)]phosphane o‐Ph2PC6H4CH2B (NMe2)2 (10) was obtained in good yields from the reaction of CIB(NMe2)2 with o‐Ph2PC6H4CH2Li(tmeda). Five derivatives of 10 were obtained by substituting the boron‐bound amino groups by reactions with MeOH, BCl3, HCl, and LiAlH4, respectively, in particular, o‐Ph2(HCl)PC6H4CH2BCl2 (HNMe2) (10 e) which shows a unique PHClHN unit. Compound 10 and its derivatives were characterized by multinuclear NMR methods, mass spectra, and elemental analyses. In addition, the structure of 10 e · 1.5 C6H6 was determined by single crystal X‐ray diffraction.

  DOI：

  10.1002/zaac.19976230714