cyclo-tri-μ-methoxo-tris(dichloroaluminium) | 72533-04-1

• 英文名称: cyclo-tri-μ-methoxo-tris(dichloroaluminium)
• CAS: 72533-04-1
• 化学式: C₃H₉Al₃Cl₆O₃
• 分子量: 386.765
• InChiKey: LNBACTGHNQANKR-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 甲基二氯化铝 以 正戊烷 为溶剂， 以79%的产率得到cyclo-tri-μ-methoxo-tris(dichloroaluminium)
  参考文献：
  名称：

  A trimeric aluminium alkoxide: methoxyaluminium dichloride

  摘要：

  The title compound, cyclo-tri-mu-methoxo-tris (dichloroaluminium), C3H9Al3Cl6O3 or [Al3Cl6(CH3O)(3)], has been characterized. Based on a six-membered [AlO](3) ring, the molecular structure is trimeric. The Al-O distances are significantly shorter than those found in structurally related organoaluminium Lewis base-acid complexes, This is a result of inductive effects due to the electronegative chlorine substituents bonded to the Al atoms.

  DOI：

  10.1107/s0108270199000505