摘要:
A number of adducts of InCl3 with selected Lewis bases have been synthesized and characterized. The complex of InCl3 with 1,2-dimethoxyethane (DME = CH3OCH2CH2OCH3) is characterized by two centrosymmetrically related InCl3 . DME . 0.5 DME units, where the indium is six-coordinated to three chlorine atoms, two oxygen atoms of one chelating DME unit and one oxygen atom of the bridging DME ligand in a fac-octahedral arrangement. The suitability and limits of using InCl3 . 3/2DME for the synthesis of InMe(3) (Me = CH3) are discussed.