[Cp*Mo(μ-SCH2COO)]2(μ-S) | 879374-42-2

• 英文名称: [Cp*Mo(μ-SCH2COO)]2(μ-S)
• 英文别名: [(C5Me5)2Mo2(μ-S)(μ-SCH2COO)2]
• CAS: 879374-42-2
• 化学式: C₂₄H₃₄Mo₂O₄S₃
• 分子量: 674.61
• InChiKey: OAGQVFUSZHVXGA-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  tetraoxo-μ-oxobis(pentamethylcyclopentadienyl)dimolybdenum(VI) 、 巯基乙酸 在 CF₃COOH 作用下， 以 甲醇 、 水 为溶剂， 以26%的产率得到[Cp*Mo(μ-SCH2COO)]2(μ-S)
  参考文献：
  名称：

  Reduction of by thioglycolic acid in an aqueous medium: Synthesis and structure of [{Cp*Mo(μ-SCH2COO)}2(μ-S)]

  摘要：

  Compound [CP*2Mo2O5] reacts with thioglycolic acid, HSCH2COOH, in an acidic (CF3COOH) mixed water-methanol solvent, to yield compound [{Cp*Mo(mu-SCH2CO2)}(2)(mu-S)]. During this reaction, the thioglycolic acid acts as a reducing agent, as a ligand, and provides a sulfide ion for the Mo-S-Mo bridge. The molecular structure of the product can be described as containing two four-legged piano stools that share three legs. The Mo-Mo distance of 2.792(7) angstrom indicates metal-metal bonding, in agreement with the compound diamagnetism. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.006