[Cu2Cl2(μ-Cl)(μ-3,5-dimethylpyrazolato)(3,5-dimethylpyrazole)4] | 758709-29-4

• 英文名称: [Cu2Cl2(μ-Cl)(μ-3,5-dimethylpyrazolato)(3,5-dimethylpyrazole)4]
• CAS: 758709-29-4
• 化学式: C₂₅H₃₉Cl₃Cu₂N₁₀
• 分子量: 713.103
• InChiKey: SHVGBJOMQNVJQE-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡唑 、 copper(II) choride dihydrate 在 NaOH 作用下， 以 四氢呋喃 为溶剂， 生成 [Cu2Cl2(μ-Cl)(μ-3,5-dimethylpyrazolato)(3,5-dimethylpyrazole)4]
  参考文献：
  名称：

  Effect of pyrazole-substitution on the structure and nuclearity of Cu(II)-pyrazolato complexes

  摘要：

  Trinuclear Cu(II)-pyrazolates of the general formula (Bu4N)(2)[Cu-3(mu(3)-Cl)(2)(mu-4-R-pz)(3)Cl-3] (pz = pyrazolato anion, R = Cl, Br, I, Me), 1-4, have been prepared and characterized by X-ray diffraction and/or H-1 NMR, IR, UV-Vis spectroscopy and elemental analysis. Their structure and spectroscopic properties match the ones of the parent unsubstituted complex (Bu4N)(2)[Cu-3(mu(3)-Cl)(2)(mu-pz)(3)Cl-3], indicating that 4-substitution of the pyrazole ligands with halogen or methyl groups does not induce structural variation. In contrast, dinuclear complexes (Bu4N)(4)[Cu-2(mu-3-Me-pz)(2)Cl-4]Cl-2 (.) 4H(2)O, Cu-2(mu-CI)(mu-3,5-Me-2-pz)(3,5-Me-2-pzH)(4)Cl-2, Cu-2(mu-Cl)(mu-OH)(3-Me-5-Ph-pzH)(4)Cl-2 (.) 3-Me-5-Ph-pzH and Cu-2(mu-Cl)(2)(3,5-Ph-2-pzH)(4)Cl-2, 5-8, have been prepared with 3- and 3,5-substituted pyrazoles by the same or similar synthetic protocols. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.03.016