[(C5Me5)W(NO)(CH2CH=CHMe)(η2-2,6-Me2C6H3N=C-n-C7H15)] | 1194440-60-2

• 英文名称: [(C5Me5)W(NO)(CH2CH=CHMe)(η2-2,6-Me2C6H3N=C-n-C7H15)]
• CAS: 1194440-60-2
• 化学式: C₃₀H₄₆N₂OW
• 分子量: 634.558
• InChiKey: VGZSVDHEWVCQCN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [(η5-C5Me5)W(η3-CH2CHCHMe)(NO)(n-heptyl)] 、 2,6-二甲基苯基异腈 以 氘代苯 为溶剂， 生成 [(C5Me5)W(NO)(CH2=CHCH(Me)N(2,6-Me2C6H3)=C-n-C7H15)] 、 [(C5Me5)W(NO)(CH2CH=CHMe)(η2-2,6-Me2C6H3N=C-n-C7H15)]
  参考文献：
  名称：

  Unprecedented Reactivity Initiated by Insertion of 2,6-Xylylisonitrile into the W−Alkyl Linkages of Cp*W(NO)(n-alkyl)(η³-CH₂CHCHMe) Complexes

  摘要：

  Treatment of the compounds Cp*W(NO)(R)(eta(3)- CH2CHCHMe) (R = n-C5H11, n-C7H15, n-C8H17) with 2,6-xylylisonitrile first produces the expected complexes bearing eta(2)-iminoacyl ligands arising from migratory insertion of the isonitrile into the tungsten-alkyl linkages, processes that result in the allyl ligands undergoing concomitant eta(3) -> eta(1) haptotropic shifts. These eta(1)-allyl complexes then undergo subsequent intramolecular nucleophilic attacks by their allyl groups on the nitrogen atoms of the eta(2)-iminoacyl ligands to form novel metallacyclic compounds that contain alpha-aminocarbene ligands.

  DOI：

  10.1021/om900739k