trans-[(μ5-C5H4PPh2)Re(CO)3]PdCl2(NCMe) | 1132793-46-4

• 英文名称: trans-[(μ5-C5H4PPh2)Re(CO)3]PdCl2(NCMe)
• CAS: 1132793-46-4
• 化学式: C₂₂H₁₇Cl₂NO₃PPdRe
• 分子量: 737.889
• InChiKey: QJYMCDPYELEMBD-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  [Pd(μ-Cl)Cl(μ5-C5H4PPh2)Re(CO)3]2*CHCl3 、 乙腈 生成 trans-[(μ5-C5H4PPh2)Re(CO)3]PdCl2(NCMe)
  参考文献：
  名称：

  Heterobimetallic Re–Pd, Re–Au and Re–Cu complexes derived from diphenylphosphino cyrhetrene: Synthesis and X-ray structure

  摘要：

  Diphenylphosphinecyrhetrene ligand (eta(5)-C5H4PPh2)Re(CO)(3) (1) reacts with 1 equiv. of PdCl2(NCPh)(2) to form, after workup, the square-planar trans-[(eta(5)-C5H4PPh2)Re(CO)(3)]PdCl2(NCMe) (2). Similarly, reaction of 1 with (tetra hydrothiophene)AuCl produces, in excellent yield, the bimetallic complex [(eta(5)-C5H4PPh2)Re(CO)(3)]AuCl (3) with a linear P-Au-Cl moiety. From the reaction of 2 equiv. of 1 with CuBr(SMe2) the planar-trigonal complex [(eta(5)-C5H4PPh2)Re(CO)(3)](2)CuBr (4) was obtained. P-31 NMR and X-ray crystallography demonstrate, for the three cases, that (eta(5)-C5H4PPh2)Re(CO)(3) acts as a monodentate ligand. The structural parameters of the bimetallic complexes are compared with related diphenylphosphinoferrocene metal complexes, described in the literature. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.10.038