[5-η5-C5Me5-arachno-5,4,6-RhC2B6H12] | 760967-61-1

• 英文名称: [5-η5-C5Me5-arachno-5,4,6-RhC2B6H12]
• CAS: 760967-61-1
• 化学式: C₁₂H₂₇B₆Rh
• 分子量: 339.118
• InChiKey: KNJDFXUPMXQDHH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 [hypho-6,7-C2B6H13][NMe4] 以 四氢呋喃 为溶剂， 以22%的产率得到[5-η5-C5Me5-arachno-5,4,6-RhC2B6H12]
  参考文献：
  名称：

  Metallacarborane chemistry of the hypho-[6,7-C2B6H13]− anion: the formation of uniquely structured metallacarboranes [5-Cp∗-arachno-5,4,6-RhC2B6H12]and[2,5-Cp2∗-10-Me-nido-2,5,1-Rh2CB6H9](Cp∗=η5-C5Me5-): complete rhodium analogues of arachno-4,6-C2B7H13 and nido-1-CB8H12

  摘要：

  Reaction of the tetramethyl ammonium salt of the hypho-[6,7-C2B6H13](-) anion (1) with the [Rh(eta(5)-C5Me5)Cl-2](2) dimer in THF solution, resulted in the formation of a novel nine-vertex metalladicarbaborane [5-Cp*-arachno-5,4,6-RhC2B6H12](2) (Cp* = eta(5)-C5Me5). An analogous reaction, but in the presence of PS (PS='proton-sponge'=1,8-bis-(dimethylamino)-naphthalene), resulted in the bimetallic nine-vertex species [2,5-Cp*(2)-10-Me-nido-2,5,1-Rh2CB6H9] (3). Compounds 2 and 3 are structural analogues of carboranes arachno-4,6-C2B7H13 (4) and nido-1-CB8H12 (5), respectively. The formation of compound 3 is associated with an extrusion of one of the cluster carbon atoms into an exo-polyhedral position and exhibits a very rare nine-vertex nido metallaborane structure with interesting features. Both species 2 and 3 were characterized by multinuclear NMR measurements and single-crystal X-ray diffraction studies. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.04.052