(meso-5,10,15,20-tetraphenylporphine)cobalt(III)Br | 60166-11-2

• 英文名称: (meso-5,10,15,20-tetraphenylporphine)cobalt(III)Br
• 英文别名: Co(5,10,15,20-tetraphenylporphinato)Br；(5,10,15,20-tetraphenylporphyrinato)bromocobalt(III)；(5,10,15,20-tetraphenylporphyrinato)CoBr；Co(tetraphenylporphyrin)Br；Co(TPP)Br；(tetraphenylporphyrin)CoBr
• CAS: 60166-11-2
• 化学式: C₄₄H₂₈BrCoN₄
• 分子量: 751.63
• InChiKey: IODIXXKDMQDDMF-YKKPBKTHSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (meso-5,10,15,20-tetraphenylporphine)cobalt(III)Br 在 吡啶 作用下， 以 氘代氯仿 为溶剂， 生成 [bis(pyridine)(meso-5,10,15,20-tetraphenylporphine)cobalt(III)]Br
  参考文献：
  名称：

  Structural studies of metalloporphyrins. 7. Proton NMR and electrochemical investigation of the (meso-5,10,15,20-tetraarylporphine)cobalt(III) complexes XCoIII(TPP-p-R)

  摘要：

  DOI：

  10.1021/ic00139a029
• 作为产物：
  描述：

  cobalt(II) 5,10,15,20-tetraphenylporphyrin 在 氢溴酸 作用下， 以 氯仿 为溶剂， 生成 (meso-5,10,15,20-tetraphenylporphine)cobalt(III)Br
  参考文献：
  名称：

  Structural studies of metalloporphyrins. 7. Proton NMR and electrochemical investigation of the (meso-5,10,15,20-tetraarylporphine)cobalt(III) complexes XCoIII(TPP-p-R)

  摘要：

  DOI：

  10.1021/ic00139a029

文献信息

• Influence of the Coordination Surrounding of Co(II)- and Co(III)-Tetraphenylporphyrins on Their Destruction Processes in the Presence of Organic Peroxides
  作者：G. M. Mamardashvili、O. R. Simonova、N. V. Chizhova、N. Zh. Mamardashvili

  DOI：10.1134/s107036321806018x

  日期：2018.6

  The interaction of Co(II)- and Co(III)-5,10,15,20-tetraphenylporphyrins with tert-butylhydroxyperoxide and di-tert-butylhydroxyperoxide in benzene at 298 K were studied by spectrophotometry and 1H NMR spectroscopy. Kinetic parameters of the destruction reactions of porphyrin macrocycle depending on the nature of peroxide the valence of cobalt cation, and the presence and nature of axial ligands were

  通过分光光度法和1 H NMR光谱研究了Co（II）-和Co（III）-5,10,15,20-四苯基卟啉与叔丁基羟基过氧化物和二叔丁基羟基过氧化物在苯中的相互作用。根据过氧化物的性质，钴阳离子的化合价以及轴向配体的存在和性质，计算了卟啉大环破坏反应的动力学参数。通过质谱确定四吡咯大环连续分解为单吡咯的产物。
• Synthesis, Structure, and Unusual Reactivity of β-Halovinyl Cobalt Porphyrin Complexes
  作者：Joseph M. Fritsch、Noah D. Retka、Kristopher McNeill

  DOI：10.1021/ic0518834

  日期：2006.3.1

  found that complex reactivity increased with the leaving group ability of the halide. A trans-dichlorovinyl cobalt porphyrin complex, (TPP)Co(Z-CClCHCl), was also prepared through the reaction of (TPP)CoNa and TCE. The structures of (TPP)Co(E-CHCHBr), (TPP)Co(Z-CClCHCl), and (TPP)Co(C(2)H) are reported. The C-C bond length of the vinyl group was found to vary for the beta-halovinyl complexes (TPP)Co(E-CHCHX)

  报道了四苯基卟啉（TPP）钴卤代戊基络合物的制备，结构和反应性。（TPP）Co（E-CHCHX）（X = Br和I）的β-卤化乙烯基络合物是通过将乙炔插入相应卤化物络合物的卤化钴键中制备的。深入研究了这些化合物与先前报道的（TPP）Co（E-CHCHCl）的反应活性，发现随着卤化物的离去基团能力，其复杂的反应活性增加。还通过（TPP）CoNa与TCE的反应制备了反式二氯乙烯基钴卟啉配合物（TPP）Co（Z-CClCHCl）。报告了（TPP）Co（E-CHCHBr），（TPP）Co（Z-CClCHCl）和（TPP）Co（C（2）H）的结构。发现β-卤代乙烯基络合物（TPP）Co（E-CHCHX）的乙烯基的CC键长度从X = Br的1.211 A变为1。X = Cl为234 A，（TPP）Co（Z-CClCHCl）为1.320A。这些结构与许多氯乙烯钴络合物的比较表明，反式-2-卤代取代会大大
• Photodecomposition of 4-Chlorophenol Catalyzed by Titanium Silicalite-2
  作者：Man Gu Kang、Jin Sup Hong、Kang-Jin Kim

  DOI：10.1246/cl.1999.885

  日期：1999.9

  The photodegradation reaction rate of 4-chlorophenol (4-CP) with a titanium silicalite–2 (TS-2) catalyst is found to be faster in the initial stage than with TiO2. This is primarily due to the stronger adsorption of 4-CP on the hydrophobic surface of the TS-2 catalyst. The hydrophobicity is evaluated by determining the distribution coefficients (D) between TS-2 and aqueous medium using a variety of aromatic hydrocarbons. The larger the D, the faster the initial reaction rate. The D correlates with solubility in water and partition coefficient, log Poct.

  与二氧化钛相比，硅酸钛-2（TS-2）催化剂对 4-氯苯酚（4-CP）的光降解反应速率在初始阶段更快。这主要是由于 4-CP 在 TS-2 催化剂疏水表面的吸附力更强。通过使用各种芳香烃确定 TS-2 和水介质之间的分配系数 (D)，可以评估疏水性。D 越大，初始反应速率越快。D 与在水中的溶解度和分配系数 log Poct 相关。
• Serendipitous synthesis of a novel cobalt(III) porphyrin phosphoryl complex
  作者：Andy K.-S. Tse、Ru-ji Wang、Thomas C. W. Mak、Kin Shing Chan

  DOI：10.1039/cc9960000173

  日期：——

  A novel complex [bis(dimethylamino)phosphoryl](5,10,15,20-tetraphenylporphyrinato)cobalt(III) 1 is synthesized serendipitously by the reaction of [CoIII(tpp)Br] with Me3SiLi (MeLi–Si2Me6–HMPA) at –78 °C in thf and its structure is characterized by a single-crystal X-ray study.

  通过[CoIII(tpp)Br]与 Me3SiLi（MeLi-Si2Me6-HMPA）在 -78 °C 的 thf 反应，偶然合成了一种新型络合物[双（二甲基氨基）磷酰]（5,10,15,20-四苯基卟啉）钴（III）1，并通过单晶 X 射线研究确定了其结构特征。
• Mahmood, Ashfaq; Liu, Hsiang-Lan; Jones, John G., Inorganic Chemistry, 1988, vol. 27, # 12, p. 2149 - 2154
  作者：Mahmood, Ashfaq、Liu, Hsiang-Lan、Jones, John G.、Edwards, John O.、Sweigart, Dwight A.

  DOI：——

  日期：——