[(μ-(C5H4(CH3)C=N-N=C(O)-2-furanyl)W(CO)3SnCl2)2(4,4'-bipyridine)] | 866554-18-9

• 英文名称: [(μ-(C5H4(CH3)C=N-N=C(O)-2-furanyl)W(CO)3SnCl2)2(4,4'-bipyridine)]
• CAS: 866554-18-9
• 化学式: C₄₀H₂₈Cl₄N₆O₁₀Sn₂W₂
• 分子量: 1499.63
• InChiKey: XYDQEOCYPPELHR-MGRIGMSXSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 [μ-(C5H4(CH3)C=N-N=C(O)-2-furanyl)W(CO)3SnCl2(H2O)] 以 二氯甲烷 为溶剂， 以93%的产率得到[(μ-(C5H4(CH3)C=N-N=C(O)-2-furanyl)W(CO)3SnCl2)2(4,4'-bipyridine)]
  参考文献：
  名称：

  Synthesis and crystal structures of cyclodiazastannoxides fused cyclopentadienyl M–Sn (M = Mo, W) bonded organometallic heterocycle

  摘要：

  The condensation reaction of CH3COC5H4M(CO)(3)SnCl3 (M = Mo or W) with PyCONHNH2 (Py = 2,3,4-pyridyl or 2-pyridylmethyl) in mild conditions yields cyclodiazastannoxides fused cyclopentadienyl M-Sn bonded organometallic heterocycle {mu-[C5H4(CH3)C=N-N=C(O)PyH]M(CO)(3)SnCl3}. The similar reaction of CH3COC5H4M(CO)(3)SnCl3 with ArCONHNH2 (Ar = 2-furanyl) gives complexes mu-[C5H4(CH3)C=N-N=C(O)Ar]M(CO)(3)SnCl2(H2O), in which the water molecule can be replaced by other N-donor ligands, such as pyridine or 4,4-bipyridine. Arene-bridged organometallic heterocyclic complexes mu-{[C5H4(CH3)C=N-N=C(O)](2)C6H4}{M(CO)(3)SnCl2(Solvent)}(2) have also been prepared by the reaction of CH3COC5H4M(CO)(3)SnCl3 with terephthaloyl hydrazine. In these new organometallic heterocyclic complexes, it seems that the tin atom prefers to be six-coordinate through absorbing the chloridion or solvent molecules. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.06.027