| 145086-14-2

• CAS: 145086-14-2
• 化学式: C₃₆H₂₈F₁₂MoN₄O₈P₄
• 分子量: 1092.46
• InChiKey: SZXCROUDGWJUMO-QQTSSPTRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (bicyclo[2.2.1]hepta-2,5-diene)tetracarbonylmolybdenum(0) 、 trans-{PhNP(OCH2CF3)}2 以 二氯甲烷 为溶剂， 以37%的产率得到
  参考文献：
  名称：

  Organometallics of diphosphazanes

  摘要：

  The reactions of cyclodiphosphazanes [PhNP(OR)]2 (R = CH2CF3 (1) and C6H4Me-p (2)) with Group 6 metal carbonyl derivatives have been investigated. The stereochemistry of the ligand appears to play a significant role in determining its coordination behaviour. The cyclodiphosphazane 1 (isolated as the trans-isomer) affords the dinuclear complexes 9-11 in which the two metal centres are bridged by the diphosphazane ligand. In contrast the cyclodiphosphazane 2 (isolated as a 3/1 mixture of cis- and trans-isomers) yields the mononuclear complexes 3-7 in which the cyclodiphosphazane is coordinated in the eta1-fashion. The structures of [W(CO4(NHC5H10){(PhNP(OC6H4Me-p))2}] (6) and [{Mo(CO)4(NHC5H10)}2{mu-[PhNP(OCH2CF3)]2}] (9a) have been determined by X-ray crystallography.

  DOI：

  10.1016/0022-328x(92)88010-g