| 175235-34-4

• CAS: 175235-34-4
• 化学式: C₁₂H₁₄Cl₄N₂Pd₂S₂
• 分子量: 605.041
• InChiKey: FSHZGZLTRTZBNA-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-甲硫基吡啶 、 以 丙酮 为溶剂， 以90%的产率得到dichloropalladium;2-methylsulfanylpyridine
  参考文献：
  名称：

  Complexes with S‐Donor Ligands, 4. Mono‐ and Di‐Homo‐ and ‐Hetero‐Nuclear Gold(I), Silver(I), and Palladium(II) Complexes with 2‐(Methylthio)pyridine, Pyridine‐2(1 H )‐thione, and Benzoxazole‐2(3 H )‐thione. Some Examples of the Use of Complexes as Ligands

  摘要：

  AbstractAgClO4 reacts with bidentate ligands 2‐(methylthio)pyridine (SMepy) or complexes PPN[Au(Spy)2] [PPN = N(PPh3)2, HSpy = pyridine‐2(1H)‐thione) or PPN[Au(Sbz)2] (HSbz = benzoxazole‐2(3H)‐thione), themselves acting as ligands, to give dinuclear complexes [Ag2(μ‐SMepy)2](ClO4)2 (1), [AgAu(μ‐Spy)2] (2), or [AgAu(μ‐Sbz)2] (3), respectively. By treating 1 with [AuCl(tht)] (tht = tetrahydrothiophene), [Au(SMepy)(tht)]ClO4 (4) is obtained which, in turn, reacts with SMepy to give [Au(SMepy)2]ClO4 (5). Similarly, [PdCl2(NCPh)2] reacts with SMepy in 1:1 molar ratio to give [Pd2Cl2(μ‐Cl)2(SMepy)2] (6) which reacts with SMepy in 1:2 molar ratio to give [PdCl2(SMepy)2] (7). On the other hand, HSpy reacts with Ag2CO3 to give [Ag2(μ‐Spy)2] (8), and (SMepyH)ClO4 reacts with [Au(acac)PPh3] (acacH = acetyl‐acetone) to give [Au(SMepy)PPh3]ClO4 (9).

  DOI：

  10.1002/cber.19961290313
• 作为产物：
  描述：

  2-甲硫基吡啶 、 二(氰基苯)二氯化钯 以 丙酮 为溶剂， 以80%的产率得到
  参考文献：
  名称：

  Complexes with S‐Donor Ligands, 4. Mono‐ and Di‐Homo‐ and ‐Hetero‐Nuclear Gold(I), Silver(I), and Palladium(II) Complexes with 2‐(Methylthio)pyridine, Pyridine‐2(1 H )‐thione, and Benzoxazole‐2(3 H )‐thione. Some Examples of the Use of Complexes as Ligands

  摘要：

  AbstractAgClO4 reacts with bidentate ligands 2‐(methylthio)pyridine (SMepy) or complexes PPN[Au(Spy)2] [PPN = N(PPh3)2, HSpy = pyridine‐2(1H)‐thione) or PPN[Au(Sbz)2] (HSbz = benzoxazole‐2(3H)‐thione), themselves acting as ligands, to give dinuclear complexes [Ag2(μ‐SMepy)2](ClO4)2 (1), [AgAu(μ‐Spy)2] (2), or [AgAu(μ‐Sbz)2] (3), respectively. By treating 1 with [AuCl(tht)] (tht = tetrahydrothiophene), [Au(SMepy)(tht)]ClO4 (4) is obtained which, in turn, reacts with SMepy to give [Au(SMepy)2]ClO4 (5). Similarly, [PdCl2(NCPh)2] reacts with SMepy in 1:1 molar ratio to give [Pd2Cl2(μ‐Cl)2(SMepy)2] (6) which reacts with SMepy in 1:2 molar ratio to give [PdCl2(SMepy)2] (7). On the other hand, HSpy reacts with Ag2CO3 to give [Ag2(μ‐Spy)2] (8), and (SMepyH)ClO4 reacts with [Au(acac)PPh3] (acacH = acetyl‐acetone) to give [Au(SMepy)PPh3]ClO4 (9).

  DOI：

  10.1002/cber.19961290313