| 1402593-16-1

• CAS: 1402593-16-1
• 化学式: C₂₉H₃₅BN₂
• 分子量: 422.421
• InChiKey: ZGMLGDALHXDACP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (2,6-ⁱPr₂C₆H₃)N(SiMe₃)Si(1,3-diisopropyl-4,5-dimethyl-imidazol-2-ylidene)Cl 以 四氢呋喃 、 正己烷 、 苯 为溶剂， 反应 53.0h， 生成 、 N-[2,6-bis(2,4,6-trimethylphenyl)phenyl]phosphanylidenesilyl-2,6-di(propan-2-yl)-N-trimethylsilylaniline
  参考文献：
  名称：

  2-Hydro-2-aminophosphasilene with N–Si–P π Conjugation

  摘要：

  The first 2-aminophosphasilene, [Ar(Me3Si)-N]HSi=PAr' (4, Ar = 2,6-iPr(2)C(6)H(3), Ar' = 2,6-Mes(2)C(6)H(3)), bearing a hydride ligand on the three-coordinate silicon atom has been synthesized and structurally characterized. Both X-ray data of 4 and DFT calculations on the model compound (H2N)HSi=PH (4') disclosed that the amino group on the silicon atom results in significant N-Si-P pi conjugation.

  DOI：

  10.1021/om3008184

文献信息

• A Multiply Functionalized Base‐Coordinated Ge^IICompound and Its Reversible Dimerization to the Digermene
  作者：Anukul Jana、Volker Huch、Henry S. Rzepa、David Scheschkewitz

  DOI：10.1002/anie.201407751

  日期：2015.1.2

  are incompatible with many functional groups. In particular, unsaturated functionalities are not tolerated owing to their facile reaction with low‐coordinate germanium compounds. We now report the synthesis of an imino‐functionalized germanium(II) species, stabilized by coordination of an N‐heterocyclic carbene (NHC), by reaction of an isonitrile with a heavier NHC‐coordinated vinylidene. Removal of the

  具有GeGe键的稳定化合物通常是在相对苛刻的反应条件下制备的，该条件与许多官能团不相容。特别是由于不饱和官能团与低价锗化合物的易反应性，因此不被允许。现在，我们报告了通过异腈与较重的NHC配位的亚乙烯基的反应，通过N-杂环卡宾（NHC）的配位而稳定的亚氨基官能化的锗（II）物种的合成。用路易斯酸除去NHC导致二聚化为具有GeGe键的相应的二锗烯。该过程的可逆性通过向分离出的狄格曼烯中添加两个当量的NHC来证明。
• Influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene
  作者：Debabrata Dhara、Shubhajit Das、Pankaj Kalita、Avijit Maiti、Swapan K. Pati、David Scheschkewitz、Vadapalli Chandrasekhar、Anukul Jana

  DOI：10.1039/c9dt04690a

  日期：——

  Irrespective of reversible coordination or non-coordination of NHC to the diphosphene; the presence of it in a stoichiometric or even in catalytic leads to the hydrolysis of diphosphene.

  无论NHC与二膦烯的可逆配位或非配位，其以化学计量比甚至催化剂存在都会导致二膦烯的水解。