[(1,1'-bis(di-iso-propylphosphino)ferrocene)PdCH3]Cl | 402475-77-8

• 英文名称: [(1,1'-bis(di-iso-propylphosphino)ferrocene)PdCH3]Cl
• 英文别名: [(1,1'-bis(diisopropylphosphino)ferrocene)Pd(CH3)Cl]；chloro(1,1'-bis(di-isopropylphosphino)ferrocene)methylpalladium(II)；[PdCl(Me)(1,1'-bis(diisopropylphosphino)ferrocene)]；[PdCl(Me)(dippf)]
• CAS: 402475-77-8
• 化学式: C₂₃H₃₉FeP₂Pd*Cl
• 分子量: 575.23
• InChiKey: TZLLQHMSWJPFAW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(1,1'-bis(di-iso-propylphosphino)ferrocene)PdCH3]Cl 、 二氧化硫 以 二氯甲烷 为溶剂， 以65%的产率得到[(1,1'-bis(diisopropylphosphino)ferrocene)Pd(SO2CH3)Cl]
  参考文献：
  名称：

  将二氧化硫插入氯（甲基）钯配合物的金属碳键中

  摘要：

  摘要已有5种氯（甲基）钯配合物（LL）Pd（Me）Cl与溶液中的SO2反应形成S-磺胺基配合物，分子式为（LL）Pd（SO2Me）Cl（LL） = dippf = 1,1'-双（二异丙基膦基）二茂铁（2），dppf =双（二苯基膦基）二茂铁（3），dppe = 1,1'-双（二苯基膦基）乙烷（4），COD（5）和（ 3,5-ditBupz）2（6））。化合物5和6在溶液中不稳定并缓慢分解。报告了（dippf）Pd（Me）Cl（1）和（dppf）Pd（SO2Me）Cl（3）的代表性晶体结构。

  DOI：

  10.1016/s0277-5387(02)01377-3
• 作为产物：
  描述：

  1,1'-bis(diisopropylphosphino)ferrocene 、 chloromethyl(1,5-cyclooctadiene)palladium(II) 以 二氯甲烷 为溶剂， 以51%的产率得到[(1,1'-bis(di-iso-propylphosphino)ferrocene)PdCH3]Cl
  参考文献：
  名称：

  将二氧化硫插入氯（甲基）钯配合物的金属碳键中

  摘要：

  摘要已有5种氯（甲基）钯配合物（LL）Pd（Me）Cl与溶液中的SO2反应形成S-磺胺基配合物，分子式为（LL）Pd（SO2Me）Cl（LL） = dippf = 1,1'-双（二异丙基膦基）二茂铁（2），dppf =双（二苯基膦基）二茂铁（3），dppe = 1,1'-双（二苯基膦基）乙烷（4），COD（5）和（ 3,5-ditBupz）2（6））。化合物5和6在溶液中不稳定并缓慢分解。报告了（dippf）Pd（Me）Cl（1）和（dppf）Pd（SO2Me）Cl（3）的代表性晶体结构。

  DOI：

  10.1016/s0277-5387(02)01377-3

文献信息

• The coordination behaviour of large natural bite angle diphosphine ligands towards methyl and 4-cyanophenylpalladium(ii) complexes
  作者：Martin A. Zuideveld、Bert H. G. Swennenhuis、Maarten D. K. Boele、Yannick Guari、Gino P. F. van Strijdonck、Joost N. H. Reek、Paul C. J. Kamer、Kees Goubitz、Jan Fraanje、Martin Lutz、Anthony L. Spek、Piet W. N. M. van Leeuwen

  DOI：10.1039/b111596k

  日期：——

  The structures of neutral and ionic 4-cyanophenylpalladium(II) and methylpalladium(II) complexes containing bidentate phosphine ligands were investigated in solution and in the solid state. Diphosphine ligands with a xanthene and a ferrocene backbone were used. New bis(dialkylphosphino) substituted Xantphos ligands were synthesised. 1H NMR and 31P NMR spectroscopy, conductivity measurements, UV-Vis spectroscopy, and X-ray crystallography were used to elucidate the structures of the complexes. Subtle changes of the phosphine ligands govern the coordination mode of the ligand. A variety of bidentate cis-, and trans-coordination and terdentate P–O–P, P–S–P and P–Fe–P coordination modes of the ligands were observed.

  研究了中性和离子型4-氰基苯钯(II)和甲基钯(II)复合物的结构，这些复合物含有双齿磷配体，并在溶液和固态进行研究。采用了以喹啉和铁烯为主链的双膦配体。合成了新的双(烷基磷基)取代的Xantphos配体。通过¹H NMR和³¹P NMR光谱、导电性测量、紫外-可见光谱和X射线晶体学来阐明复合物的结构。磷配体的微小变化决定了配体的配位方式。观察到了各种双齿顺式和反式配位以及三齿P–O–P、P–S–P和P–Fe–P配位模式。
• Ethylene Carbonylation in Methanol and in Aqueous Media by Palladium(II) Catalysts Modified with 1,1‘-Bis(dialkylphosphino)ferrocenes
  作者：Claudio Bianchini、Andrea Meli、Werner Oberhauser、Sebastien Parisel、Elisa Passaglia、Francesco Ciardelli、Oleg V. Gusev、Alexander M. Kal'si、Nikolai V. Vologdin

  DOI：10.1021/om049109w

  日期：2005.2.1

  Palladium(II) complexes with the formula [Pd(H2O)(OTs)(P-P)]OTs, where P-P is 1,1'-bis-(dimethylphosphino)ferrocene (dmpf), 1,1'-bis(diethylphosphino)ferrocene (depf), or 1,1'-bis-(diisopropylphosphino)ferrocene (dippf), have been synthesized and used to catalyze the carbonylation of ethylene in MeOH, water, or a 1/1 water/1,4-dioxane mixture. In MeOH, the reactions catalyzed by the dmpf and depf complexes gave alternating polyketone (alt-E-CO), while methyl propanoate and 3-pentanone were selectively produced with the dippf catalyst. The last catalyst was inactive in aqueous solvent. In contrast, the dmpf and depf catalysts were active in either water or water/1,4-dioxane for the copolymerization of CO with ethylene. These two catalysts were efficient also for the terpolymerization of CO with ethylene and propene in MeOH or water/1,4-dioxane. Operando high-pressure NMR experiments and in situ reactions with model compounds have provided useful information to rationalize the activity and selectivity of the catalytic systems investigated.
• Palladium(II) complexes containing symmetrical diphosphine ligands based on ferrocene. Sterically enforced palladiumiron bonds
  作者：Martin A Zuideveld、Bert H.G Swennenhuis、Paul C.J Kamer、Piet W.N.M van Leeuwen

  DOI：10.1016/s0022-328x(01)00970-6

  日期：2001.12

  Methylpalladium chloride, cationic methyl- and acylpalladium triflate complexes were synthesised containing bis(dialkyl) and bis(diphenyl)phosphine ferrocene ligands. Trans-coordinated cationic methylpalladium complexes containing 1,1'-bis(di-tert-butylphosphino)ferrocene, form a palladium-iron bond. The less bulky 1,1'-bis(di-iso-propylphosphino)ferrocene ligand coordinates in a cis fashion in methylpalladium chloride complexes. A palladium-iron bond was indicated in the cationic acylpalladium. complexes of both alkylphosphine ligands. 1,1'-Bis(diphenylphosphino)ferrocene does not form a palladium-iron bond in the monocationic acyl- and methylpalladium complexes. The complexes were characterised by H-1-, P-31-, C-13-NMR spectroscopy, kelemental analysis, and UV-vis spectroscopy. (C) 2001 Elsevier Science B.V. All rights reserved.