[MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(CONHCH2)C=CH2)]2 | 186651-82-1

• 英文名称: [MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(CONHCH2)C=CH2)]2
• 英文别名: [MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2(OCNHCH2)C=CH2)]2
• CAS: 186651-82-1
• 化学式: C₄₀H₃₀Cl₂Mo₂N₆O₆
• 分子量: 953.501
• InChiKey: UEGGNWZVALOEEB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(COCl)C=CH2) 、 乙二胺 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以62%的产率得到[MoCl(CO)2(1,10-phenanthroline)(η(3)-CH2C(CONHCH2)C=CH2)]2
  参考文献：
  名称：

  Synthesis and characterisation of monomeric and dimeric 2-substituted η3-bonded butadienyl complexes of molybdenum(II)

  摘要：

  Addition of excess thiol RSH (R = Et, Pr-n, Pr-i, (n)Bu or (i)Bu) to solutions of [MoCl(CO)(2)(eta(3)-CH2C(COCl)C=CH2)(phen)] (1) (phen = 1,10-phenanthroline) gave good yields of the complexes [MoCl(CO)(2)(eta(3)-CH2C(COSR)C=CH2)(phen)], containing a 2-substituted butadienyl ligand. On reaction of 1 with 1,2-ethanedithiol in 2:1 molar ratio under basic conditions, dimeric complexes were obtained containing two metal centres bridged by a pair of 2-substituted butadienyl groups linked by the dithiol unit. Analogous dimeric complexes containing linked amido eta(3)-butadienyl groups were isolated from a similar 2:1 reaction of 1 and diamines RHN(CH2)(2)NHR (R = H or Me). However, reactions involving 1 and mixed bifunctional reactants HA(CH2)(2)BH (A = NH, B = O, S or A = O, B = S) under the same conditions gave monomeric complexes exclusively, the less electonegative atom of the donor pair remaining unreacted.

  DOI：

  10.1016/s0022-328x(96)06450-9

文献信息

• Dimeric and trimeric molybdenum(II) complexes containing 2-substituted η3-bonded butadienyl bridging ligands
  作者：Annabelle G.W. Hodson

  DOI：10.1016/s0022-328x(97)00456-7

  日期：1997.12

  ratio gave dimeric complexes [MoCl(CO)2(η3-CH2(COACH2)C=CH2)phen]2 containing two molybdenum centres bridged by a pair of η3-bonded butadienyl units linked by 2-substituted ester (A = O) or amide (A = NEt) groups. Analogous reactions involving hydroquinone or 1,4-phenylenediamine led to monomeric complexes of the type [MoCl(CO)2(η3-CH2(COA)C=CH2)phen] (A = OC6H4OH, NHC6H4NH2), however, dimeric complexes

  的反应[代替MoCl（CO）2（η 3 -CH 2（氯化钴）C = CH 2）苯]（苯= 1,10-菲咯啉）（1）与1,2-乙二醇或N，N- '-diethylethylenediamine在2：1的摩尔比，得到的二聚配合物[代替MoCl（CO）2（η 3 -CH 2（COACH 2）C = CH 2）苯] 2个含有两个钼中心桥接由一对η 3通过2-取代的酯（A = O）或酰胺（A = NEt）基团连接的键合丁二烯基单元。涉及氢醌或1,4-苯二胺引发的类型[代替MoCl（CO）的单体配合物的类似反应2（η 3 -CH 2（COA）C = CH 2）苯]（A = OC 6 H ^ 4 OH，NHC 6然而，从涉及4,4'-亚乙基二苯胺或对苯二甲撑二胺的反应中分离出二聚配合物H 4 NH 2）。尝试使用二亚乙基三胺制备由三个连接的酰胺取代的丁二烯基桥接的新型配合物，但是，反应1在3和三乙醇胺或